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Analytical Microscopy and Imaging Science

An image of interconnecting yellow and red particles

NREL uses transmission/scanning electron and scanning probe techniques to measure the chemical, structural, morphological, electrical, interfacial, and luminescent properties on the nano to Angstrom scale.

We investigate such properties in a wide range of photovoltaic and semiconducting materials, with particular emphasis on extended defects and interfaces and how these affect device performance. A powerful approach for further device improvements is the linking of nano- and sub-nanoscale material and device properties to macro-scale device performance.

Capabilities


Transmission and Scanning Transmission Electron Microscopy

We investigate the structure and chemistry of a wide range of materials, with particular emphasis on the structure and chemistry associated with defects and interfaces using transmission electron microscopy (TEM) and scanning TEM (S/TEM). This is particularly useful for determining how the microstructure affects derived material properties. Our microscopes are equipped to perform diffraction contrast, higher-resolution phase-contrast microscopy, high-angle annular dark-field (HAADF) microscopy, nanodiffraction, convergent beam electron diffraction, energy-dispersive X-ray spectroscopy (EDS), and electron energy-loss spectroscopy (EELS).

Contacts:
Andrew Norman  | Email | 303-384-6483

Jeffery Aguiar | Email | 303-384-6485


Focused Ion Beam Milling

Our FEI Nova 200 Nanolab is used for multiple tasks at NREL. The primary task is sample preparation for high-resolution TEM/STEM analysis. Coupled with the in-situ electron beam induced current capabilities, this allows for extraction of specific features deemed detrimental to device performance such as grain boundaries, dislocations, and interfaces. This tool is also used for fiduciary marking, preparation of cross-sections for SEM imaging, and preparation of samples for cutting-edge SEM-based analysis. In addition, this instrument is equipped with electron backscatter diffraction (EBSD) and EDS capabilities, and it can operate in the temperature range of 300 K to 80 K.

Contact: Harvey Guthrey | Email | 303-384-6232


Electron Probe Microanalysis

Our JEOL 8900 Super Probe is used to provide Electron Probe Microanalysis (EPMA) for quantitative compositional analysis. It relies on wavelength-dispersive spectroscopy to identify and quantify elemental composition with a high degree of accuracy. Profiling against standards we have available, the EPMA covers the majority of the periodic table from boron to bismuth. Detection limits and sensitivity for the EPMA are in the 0.5%–1% atomic weight percentage range.

Contact: Bobby To | Email | 303-384-6704


Scanning Electron Microscopy

We use field-emission SEM (FESEM) to analyze the morphology/microstructure with high-spatial resolution (up to 1.2 nm). Backscattered-electrons (BSE) mode allows for elemental-sensitive imaging.

We use electron backscatter diffraction (EBSD) to analyze the crystallographic and structural properties, including texture, boundaries, and grain size. Capabilities include orientation maps that produce images of the crystallographic orientation of the sample surface with angle resolution of 0.1°, and spatial resolution as high as 10 nm.

Energy-dispersive X-ray diffraction spectroscopy (EDS) is used for standardless compositional analysis and can identify all elements above beryllium (Z=4), in spot, line, and mapping mode, with sensitivity as low as 0.5 weight %.

Contact: Helio Moutinho | Email | 303-384-6457


Cathodoluminescence, Electron-Beam-Induced Current

Cathodoluminescence (CL) and electron-beam-induced current (EBIC) are SEM-based characterization techniques that use the electron beam to generate electron-hole pairs for imaging the electrical and optical properties of semiconductors with high spatial resolution.

They are used to investigate the distribution of recombination centers in semiconductors, including extended defects such as dislocations and grain boundaries, stress fields, compositional fluctuations, and other important features—with an ultimate spatial resolution of about 50 nm. Our 6K cryogenic stage allows an energy resolution that is comparable to low-temperature photoluminescence (PL).

Contact: Harvey Guthrey | Email | 303-384-6232


Scanning Probe Microscopy Platforms

We can perform surface morphology and structure determination, nm-resolution imaging of electrical inhomogeneity, and nm-scale junction and defect studies. The platforms include atomic force microscopy (AFM) for surface morphology; Kelvin probe force microscopy (KPFM) for electrical potential, scanning spreading resistance microscopy (SSRM)/conductive-AFM (C-AFM) for local resistivity; scanning capacitance microscopy (SCM)/scanning capacitance spectroscopy (SCS) for carrier distribution; scanning tunneling microscopy/spectroscopy (STM/STS) for atomic/electronic structures; and near-field scanning optical microscopy (NSOM) for transport imaging by combining with e-beam exciting of minority carriers.

Contact: Chun-Sheng Jiang | Email | 303-384-6687


Contact

Photo of Dr. Mowafak Al-Jassim, who manages the Analytical Microscopy and Imaging Science group in NREL's Materials Science Center.

Mowafak Al-Jassim

Group Manager

Dr. Al-Jassim manages the Analytical Microscopy and Imaging Science group with the Materials Science Center.

Email | 303-384-6602


The Materials Science Center is part of the Materials and Chemical Science and Technology directorate, led by Associate Lab Director Bill Tumas.