Cell Measurements

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Cell measurements at NREL include spectral responsivity and current versus voltage (I-V) of one sun, concentrator, and multijunction devices. Reference cell measurements also include linearity of short-circuit current and total irradiance.

Cell Current versus Voltage

We use I-V measurement systems to assess the main performance parameters for PV cells and modules. I-V measurement systems determine the output performance of devices, including open-circuit voltage (Voc), short-circuit current (Isc), fill factor (FF), maximum power output of the device (Pmax), voltage at maximum power (Vmax), current at maximum power (Imax), and conversion efficiency of the device (η). Some I-V systems may also be used to perform dark I-V measurements to determine diode properties and series and shunt resistances.

All I-V systems use data acquisition systems and custom software for accurate standardized PV measurements. This includes algorithms developed by our group over the years for calculating I-V characteristics and spectral-mismatch corrections. The custom I-V systems and flash simulators use separate 6½-digit multimeters or high-speed analog-to-digital converters for measuring voltage, current, and intensity; this allows us to correct the current for intensity fluctuations. The systems all have multiple current ranges, allowing a wide variety of commercial and prototype cells and modules to be measured routinely.

For non-concentrator solar cells and multijunction devices, we use:

  • Abet 11048 solar simulator
  • One-sun multisource solar simulator.

For concentrator solar cells, we use:

  • Tunable high-intensity pulsed solar simulator
  • High-intensity pulsed polar simulator
  • Continuous illumination concentrator simulation system.

The following table provides a condensed list of characteristics for cell I-V measurement test beds.

Major Instrumentation for Cell I-V Measurements
System Typical Applications Special Features Light Source Test Bed Voltage Resolution / Limit Current Resolution / Limit
System

Abet 11048 solar simulator

Typical Applications

1-sun I-V measurements for cells and small modules

Special Features

Wide current and voltage ranges

Light Source

Filtered 3-kW xenon lamp; 0.1 to ˜10 suns

Test Bed

30 cm diameter; 15° to 50°C

Voltage Resolution / Limit

5 µV / ±50 V

Current Resolution / Limit

±10 pA to ±16 A

One-sun multisource simulator 

Typical Applications

Multijunction cells, I-V versus irradiance and temperature

Special Features

10 separate adjustable wavelength bands; dedicated spectroradiometer

Light Source

2 xenon and 2 tungsten lamps; fiber optic; up to 1.37 suns

Test Bed

9 cm × 9 cm; 10° to 80°C

Voltage Resolution / Limit

0.1 µV / ±40 V

Current Resolution / Limit

1 nA to ±5 A

System

Tunable high-intensity pulsed solar simulator 

Typical Applications

I-V measurements for concentrator and thermophotovoltaic cells

Special Features

Spectrally adjustable; ˜1-ms flash; minimal heating; dedicated spectroradiometer

Light Source

2 xenon flash lamps 30 cm long with mirror; 1 to ˜600 suns

Test Bed

4 cm × 4 cm, <1 cm2 typical); 15° to 80°C

Voltage Resolution / Limit

0.1 mV / 20 V

Current Resolution / Limit

100 µA to 20 A

System

High-intensity pulsed solar simulator

Typical Applications

I-V measurements for concentrator and thermophotovoltaic cells

Special Features

˜1-ms flash; minimal heating

Light Source

2 xenon flash lamps 30 cm long with mirror; 1 to 2000 suns

Test Bed

10 cm × 10 cm; 5° to 80°C

Voltage Resolution / Limit

0.1 mV / 100 V

Current Resolution / Limit

500 µA to 50 A

System

Continuous illumination concentrator simulation system

Typical Applications

I-V measurements for concentrator cells

Special Features

User-controlled bias conditions

Light Source

1-kW xenon lamp or 3-kW tungsten lamp; 0.1 to 200 suns

Test Bed

˜1-cm diameter for xenon; 5° to 80°C

Voltage Resolution / Limit

5 µV / ±10 V

Current Resolution / Limit

±1 µA to ±10 A

Spectral Responsivity

Spectral responsivity measurement is an important part of the NREL photovoltaic device performance assessment process. Spectral responsivity systems measure how a device responds to selected narrow (spectral) bands of irradiance. Responsivity is measured in units of amps per watt versus wavelength and reported in terms of quantum efficiency—a measure of how efficiently a device converts incoming photons to charge carriers in an external circuit.

We use two spectral responsivity systems:

  • Filter system
  • Grating system.

The following table is a condensed list of major instrumentation characteristics for spectral response measurements.

Major Instrumentation for Spectral Response Measurements

System

Typical Applications

Special Features

Light Source

Wavelength Range

 

Bandwidth

Voltage Bias

Light Bias

System

Filter spectral responsivity

Typical Applications

Spectral responsivity measurements for solar cells and modules; 15°C to 80°C

Special Features

High flux density; variable beam size; 61 filters on four filter wheels; adjustable chopping frequency

Light Source

1-kW xenon lamp

Wavelength Range

 

280 to 1,900 nm

Bandwidth

10 nm full width at half maximum

Voltage Bias

±40 V

Light Bias

Up to 200 mA

System

Grating spectral responsivity

Typical Applications

Spectral responsivity measurements for small-area and multijunction cells; 15°C to 80°C

Special Features

3 gratings for visible and infrared; adjustable chopping frequency

Light Source

75-W xenon lamp

Wavelength Range

 

300 to 3,000 nm

Bandwidth

>1 nm full width at half maximum

Voltage Bias

±5 V

Light Bias

Up to 200 mA

Linearity

The linearity of the short-circuit current (Isc) with total irradiance is an important measurement for reference cells because the standards require the reference cell to be linear over its range of operation. NREL measures the linearity of Isc in the range of 0 to 2 suns using two lamps and neutral-density filters. If the sample is linear, then the Isc from one lamp plus the Isc from the other lamp must equal the Isc when both lamps are on. This value is expressed as a percentage deviation from linearity and is typically measured over the range of 0.1 to 1.1 sun. This method is insensitive to the spectrum and spatial nonuniformity of the light from the two lamps at varying light levels.


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