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Surface Analysis Cluster Tool

Floor plan showing where surface analysis cluster equipment sits.

Schematic diagram of the surface analysis cluster tool.

Photograph of the Surface Analysis Cluster Tool

The surface analysis cluster tool was designed and built by NREL for the in-situ study of surface and chemical changes.

Residing in our new Science and Technology Facility (S&TF), is the surface analysis cluster tool that the National Renewable Energy Laboratory recently designed and built for the in-situ study of surface chemical changes that occur during growth and processing of materials under various conditions. This tool enables us to better understand reactions and kinetic processes at surfaces. By using an ultra high-vacuum trolley system, we took our previously stand-alone X-ray photoelectron spectroscopy/ultraviolet photoelectron spectroscopy and auger electron spectroscopy instruments and joined them to a custom ultrahigh-vacuum thin-film deposition system and a nitrogen-ambient glovebox. The result is our ultrahigh-vacuum cluster tool that allows controlled surface modification and processing in addition to new analysis tools that include thermal desorption mass spectrometry, reflection high-energy electron diffraction, low-energy electron diffraction, and the capability for in-situ spectroscopic ellipsometry during film deposition.

The cluster tool can be used to study the effect of various chemical treatments on surface composition without compromising the treated surface by exposing it to air prior to analysis. Here we illustrate the surface cleaning effect of an aqueous ammonia treatment on a Cu(In,Ga)Se2 surface. Aqueous ammonia is a component of the chemical bath used to deposit CdS for CIGS device formation. The as-received film was exposed to aqueous ammonia in our glove box and then transferred directly to the XPS via the transfer system without exposure to air. The spectra show the surface oxygen contamination is removed and the metal content of the clean surface approaches that of the bulk film.

Spectra from an as-received (in red) Cu(In,Ga)Se surface are compared to spectra from the aqueous ammonia treated (in black) surface.

For additional information contact Pete Sheldon, 303-384-6553.